Tetra­aqua­bis[3-(3-pyrid­yl)-5-(4-pyrid­yl)-1,2,4-triazolido]nickel(II) dihydrate

نویسندگان

  • Yun-Liang Zhang
  • Ti-Lou Liu
  • Shuang-Jiao Sun
چکیده

In the title compound, [Ni(C(12)H(8)N(5))(2)(H(2)O)(4)]·2H(2)O, the Ni(II) atom is coordinated by the two N atoms [Ni-N = 2.094 (3) Å] and four O atoms [Ni-O = 2.063 (3)-2.083 (2) Å] in a distorted octa-hedral geometry. The mol-ecule is centrosymmetric and the Ni(II) atom is located on an inversion center. Inter-molecular O-H⋯N and O-H⋯O hydrogen bonds link the complex into a three-dimensional supra-molecular framework.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Diaqua­bis­(3-nitro­benzoato-κO 1)bis­[1H-5-(3-pyrid­yl)-3-(4-pyrid­yl)-1H-1,2,4-triazole-κN 5]cobalt(II) dihydrate

In the centrosymmetric title compound, [Co(C(7)H(4)NO(4))(2)(C(12)H(9)N(5))(2)(H(2)O)(2)]·2H(2)O, the Co(II) atom, located on an inversion center, is coordinated by two N atoms [Co-N = 2.155 (3) Å] and four O atoms [Co-O = 2.099 (2)-2.117 (3) Å] in a distorted octa-hedral geometry. Inter-molecular N-H⋯O, O-H⋯N and O-H⋯O hydrogen bonds link the components into a three-dimensional supramolecular ...

متن کامل

(Ethyl­enediamine-κ2 N,N′)bis­[3-(2-pyridyl)-5-(4-pyrid­yl)-1,2,4-triazolato-κ2 N 2,N 3]zinc(II) methanol solvate dihydrate

The asymmetric unit of the title compound, [Zn(C(12)H(8)N(5))(2)(C(2)H(8)N(2))]·CH(3)OH·2H(2)O, contains a Zn(II) cation, octahedrally coordinated by two 3-(2-pyrid-yl)-5-(4-pyrid-yl)-1,2,4-triazolate anions, a chelating ethane-1,2-diamine mol-ecule, a methanol solvent mol-ecule, and two crystal water mol-ecules. In the crystal packing, complex mol-ecules are linked by hydrogen bonds into a two...

متن کامل

Tetra­aqua­bis(3,5-di-4-pyridyl-1H-1,2,4-triazolido)cadmium(II) dihydrate

In the title compound, [Cd(C(12)H(8)N(5))(2)(H(2)O)(4)]·2H(2)O, the Cd(II) atom is located on an inversion center and is coordinated by the two N atoms [Cd-N = 2.278 (2) Å] and four O atoms [Cd-O = 2.304 (2)-2.322 (2) Å] in a distorted octa-hedral geometry. Inter-molecular O-H⋯O and O-H⋯N hydrogen bonds link the complex into a three-dimensional supra-molecular framework.

متن کامل

Bis(2-hy­droxy­benzoato-κO)bis­[3-(4-meth­oxy­phen­yl)-4-(4-methyl­phen­yl)-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ2 N 1,N 5]copper(II) dihydrate

In the title complex, [Cu(C(7)H(5)O(3))(2)(C(21)H(18)N(4)O)(2)]·2H(2)O, the Cu(II) atom is located on a centre of inversion and exists in a tetra-gonally distorted octahedral geometry with a CuN(4)O(2) chromophore. The intra-molecular O-H⋯O hydrogen bond is highly strained due to the mol-ecular geometry and, as a result, is much shorter than expected. Inter-molecular C-H⋯O and C-H⋯O inter-actio...

متن کامل

Tetra­aqua­bis{2-[4-(3-pyrid­yl)pyrimidin-2-ylsulfan­yl]acetato}manganese(II) dihydrate

In the title compound, [Mn(C(11)H(8)N(3)O(2)S)(2)(H(2)O)(4)]·2H(2)O, the Mn(II) ion lies on an inversion centre and is coordinated by four water mol-ecules in equatorial positions and two N atoms from two 2-[4-(3-pyrid-yl)pyrimidin-2-ylsulfan-yl]acetate ligands in the axial positions. The water mol-ecules, including the uncoordinated water mol-ecules, and the acetate O atoms are involved in O-H...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 65  شماره 

صفحات  -

تاریخ انتشار 2009